The vibration of the formaldehyde molecule is composed of six normal modes. Two modes are stretching the molecule along the covalently bound C and H in the σvxz relfection plane. One mode is stretching the molecule along the covalently bound C and O in the σvxz plane, while bending the entire molecule in the same plane. Two other modes are bending the molecule in the σvxz reflection plane, while the remaining mode is bending the molecule out of this plane. The stretching ν1(A1) and ν2(A1), as well as the deformations ν3(A1) and ν6(B2) are symmetric with respect to the σvyz reflection plane, while the stretching mode ν4(B1) and the deformation ν6(B2) are antisymmetric.
Formaldehyde is in the C2v point group with the symmetry elements: C2 axis (black), σvxz plane (cyan) and σvyz plane (yellow). [compare to water in symotter-gallery]
ν4(B1) | νasCH
antisymmetric stretching
ν1(A1) | νsCH
symmetric stretching
ν2(A1) | νCO
stretching
ν3(A1) | δsCH
"scissor bending"
ν5(B1) | δasCH
"rocking"
ν6(B2) | δsOH
"wagging"