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vibrations frequencies spectrum

The vibration of the carbon dioxide molecule is composed of four normal modes. Two modes are stretching the molecule along the covalently bound C and O. The other two are bending the linear molecule, basically changing the angle α(O-C-O). The bending modes are degenerate (they have the same vibrational frequency), which makes them indistinguishable in usual experiments. Thus, we only speak of one bending mode ν2(E1u). The stretching mode ν3(A1u) and the bending mode ν2(E1) are anti-symmetric with respect to the inversion center, while the stretching mode ν1(A1g) is symmetric. pg Carbon dioxide is in the D∞h point group with the symmetry elements: S2 and C axes (black), infinite σv planes (cyan), infinite C2 axes, inversion center. [check symotter-gallery]

normal modes of the carbon dioxide molecule

mode4

ν3(A1u) | νasCO

antisymmetric stretching

mode3

ν1(A1g) | νsCO

symmetric stretching

mode2

ν2(E1u) | δsCO

bending

mod1

ν2(E1u) | δsCO

bending